Not really. Both are ways to perform deterministic resource management, but RAII is a branch of deterministic resource management which most GC'd languages can not use as they don't have deterministic object lifetimes.

This is inspired by similar constructs in Java, C#, and Python (and in fact lifted from C# with some adaptation to JS's capabilities), and insofar as those were related to RAII, they were a step away from it, at least when it comes to Python: CPython historically did its resource management using destructors which would mostly be reliably and deterministically called on refcount falling to zero.

However,

1. this was an issue for non-refcounted alternative implementations of Python

2. this was an issue for the possibility of an eventual (if unlikely) move away from refcounting in CPython

3. destructors interact in awkward ways with reference cycles

4. even in a reference-counted language, destructors share common finaliser issues like object resurrection

Thus Python ended up introducing context managers as a means of deterministic resource management, and issuing guidance to avoid relying on refcounting and RAII style management.