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Panel with photovoltaic material layered on silicon hits 33% efficiencies (arstechnica.com)
198 points by mfiguiere on July 8, 2023 | hide | past | favorite | 172 comments


We should all take a moment and appreciate that plants are pegged to (IIRC) 10-15% theoretical max efficiency, and that's just in photocapture, it's even worse when you factor in chemical inefficies in storage and conversion of sugars back to usable atp (which it must do to use the energy)


> plants are pegged to (IIRC) 10-15% theoretical max efficiency...

OTOH, plants (i.e. trees) can live for hundreds of years, they are self-replicating, they extract their own minerals from the ground, require very little energy input to put in place, play an crucial role in the water cycle [1], reduce the albedo effect [2], cool the air [3], provide a habitat for a multitude of species, and bring joy to our hearts.

Oh, I almost forgot, they also fix carbon! And they do all this for free, the only thing you have to do is, you know, not cut them down.

I would say that's a pretty good deal.

[1] https://sustainablefootprint.org/nederlands-trees-and-the-wa... [2] https://en.wikipedia.org/wiki/Albedo#Trees [3] https://www.epa.gov/heatislands/using-trees-and-vegetation-r...


And they make Oxygen...


That's absolutely vital on a space colony; on Earth, we're dead from CO2 toxicity well before we can't breathe from insufficient oxygen.


> plants are pegged to (IIRC) 10-15% theoretical max efficiency

I suspect this is soon to change.... With CO2 levels around 280 ppm, the biggest challenge for many plants is finding a carbon atom - in fact, many plants grow just as fast under just 10% brightness sunlight.

Now that CO2 is up at 420 ppm, it's far easier to find carbon, so now the evolutionary race will be on to collect more sunlight and grow faster. And plants have done this before, ~20 million years ago, so somewhere there are probably some recessive genes just waiting for their moment to shine again, and natural selection will make them spread like wildfire.


If it was just CO2 levels going up then maybe. The problem is that temperatures are going up too, so gas solubility is going down. This means that C4 or CAM photosynthesis plants might get an edge over C3 on a larger area.


We’d have to assume that due to the greenhouse effect , the earth was also hotter then ?


20mln years ago the sun was around 0,2% colder, which isn't a lot, but still more than variability from solar cycles.


Do you have a source on that? We have been in an ice age for roughly the past million years. Pretty sure it was warmer in almost every other era prior.


> > 20mln years ago the sun was around 0,2% colder

> Do you have a source on that?

It's not solar radiation forcing that has made things relatively cooler, but it is cooler than 20M years ago. Of course, we could actually reach those temperatures again soon.

https://environmental-geology-dev.pressbooks.tru.ca/chapter/...

See fig 3.1.2.

"The present rate of solar warming is about 8% every billion years. That’s 0.008% every million years or 0.0000008% every century."


"Soon" on an evolutionary scale could still mean hundreds if not thousands of years.

For example, wood is a great food resource for fungi, but it took millions of years for wood-eating fungi to evolve after wood.


It's complicated! My bet would be less on individual species slowly adapting, and more on mass extinction and re-specialization.

When there's a big shock, specialists have a harder time, and generalist species have an edge. So, when an ecosystem is destabilized or totally transformed, generalists tend to take over. The thing about generalists is that they adapt to new environments quickly. Once they live stably in a new environment long enough, they begin to adapt to it more stably, and specialize, leading to new speciation.

Songbirds are a great example of this; they exploded out of Australia some 40 million years ago, spread everywhere, and then specialized like crazy into their new environments. They likely out-competed a lot of pre-existing local species as they spread out. Humans are also a great example - we spread everywhere as successful generalists, and started the process of biologically specializing in our new environments without fully speciating. In the case of humans, we know pretty precisely about the wave of megafauna extinctions that accompanied our spread.


The Younger Dryas megafauna extinctions cannot necessarily be attributed to humans. Humans spread tens of thousands of years ago. And numerous megafauna still exist in Africa, the likely birth place of humanity.


Well... lots more here. My impression was that African mammals survived in part because they co-evolved with humanity, and didn't get quite the shock as other places where humans showed up fully formed.

https://en.wikipedia.org/wiki/Holocene_extinction#Historic_e...

Wild mammal biomass is estimated to be about 83% lower due to humans. Reduction in biomass isn't exactly synonymous with extinction, but they aren't totally unrelated either.

https://www.theguardian.com/environment/2018/may/21/human-ra...


What are the alternative hypothesis?


There's an impact meteor hypothesis, disease, super volcano, and the rapid seesaw climate change itself.

https://blogs.scientificamerican.com/history-of-geology/http...


There aren't any unless you're an incredibly fringe academic or using dumb terminology to avoid admitting that strong multiregionalism is entirely dead. Human evolution didn't stop there and there are unresolved questions about where within Africa different phases of the process occurred, of course, but the continent as a whole is undoubtedly where anatomically modern humans emerged.


Yep. I remember being blown away when I learned that most early trees fossilized because there was nothing yet to break them down. Not fungi, not bacteria, not insects.


Pretty crazy to imagine. large swaths of land with layers and layers of fallen trees


Most of them would have broken down, it's not like giant piles of logs. Think more "heavily wooded bog"


If there was oxygen, it still burned. One lightning strike would be enough to wipe the ground clean.


There was much less oxygen back then.


This was the Carboniferous age when oxygen levels are thought to have been up to 35% as opposed to 21% now.

Most trees probably grew in swampy areas and the water they fell into would have been lower in oxygen. The material would have built up in the water and mud.


The weather still breaks down dead plant matter, even without fungi or insects, I think?


Yes, it turned to mud, then oil.


The evolutionary lag hypothesis is trivially false. Simple calculations show you’d quickly run out of atmospheric carbon.


I mean, we did?

Atmospheric CO2 levels in the pre-tree era 400 Myears ago was something like above 6000ppm, compared to 280ppm in the pre-industrial era. Even burning coal formed during this time like mad, 90% of the atmospheric CO2 is still just gone.


So, can you provide the calculations?


Could mean a long time, or could not. There have been new bacteria/fungi discovered around chernobyl which subsist on gamma radiation. It's not like evolution of new processes are guaranteed to happen slowly, it just seems unlikely to happen quickly.

https://en.wikipedia.org/wiki/Radiotrophic_fungus


Many of the photosynthesizing algae can complete a lifecycle in 8 hours. They should be able to evolve pretty quick to new conditions, especially across the huge volume of ocean water.

Trees and stuff will be far slower, yes.


10% is the theoretical quantum efficiency of the chlorophyll complex. Ps I/II use all sorts of tricks to squeeze electrons out of light, it's hard to imagine it getting better.

Remember that photosynthesis is a two stroke process. Fixing carbon tends to happen at night, so both sides are subject to optimization, and the day side has way more variation (seasonal etc) so you can't just say "RuBisCo sucks so PSI/II must be very suboptimal".


I predict 1000 years from now, CO2 will be up near 700 ppm and biomass will grow ~15% faster on average, but some plants will grow at 100% faster.


No need to predict this. Greenhouse experiments are conducted regularly with these conditions. There's plenty of data on it.


This Friday there was severe thunder and rain around here while the forecast said no rain at all. The reason was, they had 3 different models running and all of them gave the whole week different results (basically no overlap), so they just took the most probable, which was totally wrong.

I know these models are not that mich related, but when we can't look at the wheather of tomorrow, I question the precision of a model looking 1000 years into the future a bit. It will get warmer, for sure. But _how much_ is IMHO subject to interpretation.


> I know these models are not that mich related, but when we can't look at the wheather of tomorrow, I question the precision of a model looking 1000 years into the future a bit. It will get warmer, for sure. But _how much_ is IMHO subject to interpretation.

You say you know these models aren't that much related, but you still question the precision based on weather models. So do you, or do you not think they are much related?

If you throw a marble into a pit I can't easily predict which path it will take, but I can tell you where it will end up with which likelihood.


It’s very hard to predict a single coin flip accurately, it’s extremely easy to predict the averages over a thousand coin flips.


You can test individual plants, but it's hard to test the effect of evolution in a greenhouse unless you want to wait 1000 years...


Evolution takes a lot longer than 1000 years to affect fundamental processes like photosynthesis, which is an ancient biological chemical reaction. Plants experienced thousands of ppm of CO2 and warmer temperatures for most of Earth's 1 billion plus year history. The fossil fuels that are being burned, the carbon that is being burned, is dead plant matter from millions of years ago, when CO2 was thousands of ppm.


I bet you $1000 USD you're wrong.


Not a smart bet to take when the experiment has already been conducted thousands of times:

https://bmcplantbiol.biomedcentral.com/articles/10.1186/s128...

https://extension.okstate.edu/fact-sheets/greenhouse-carbon-...

This isn't new knowledge. We've known this for over 100 years.

"An increase in ambient CO2 to 800-1000 ppm can increase yield of C3 plants up to 40 to 100 percent and C4 plants by 10 to 25 percent while keeping other inputs at an optimum level."


Since neither of them will be alive in 1000 years to collect, it is rather moot, no?


It's mostly a joke on that basis, but I am a little skeptical that the well-known CO2 experiments will apply on average across the globe without being counteracted in part or whole by the temperature & growing season impacts.

In our current breadbaskets plants are going to be losing a chunk of the day in the middle of the growing season when it is too hot to photosynthesize on a regular basis, and the tradeoffs of what land is desertified and what land is defrosted is unlikely to be a net gain. The gains from increased CO2 are starting from in a hole and I'm not expecting to break even, let alone see faster or greater biomass on average, let alone at the rate we see in experiments using our current climate and future CO2 levels.


We have two main types of human corn here (Quebec). Yellow corn, and bi-colour corn.

Yellow corn literally does not come to full harvest if there are too many cloudy days. This happens once a decade maybe. It needs a growing season longer, and with more light than we have here.

Just 300km further south, in Ontario, this is not a problem.

(Bear in mind that the days shorten fast as fall approaches here)

Bi-colour corn can get two crops.

My point is, we already... without genetic engineering, just by selective breeding, get wild variations in growth rate, and yields, and harvest times... with just a decade or two of selective breeding work!

And my second point is, the most fertile land is going to become usable, if temps continue to rise. All that bog in Northern Canada.

We just need crops suited to shorter growing seasons, and very long days at equinox.

Canada is already mostly farmland. It will be interesting to see where this goes.


Re: selective breeding and genetic engineering, that's going to happen regardless of the atmospheric carbon levels.

Also, while I did bring up agriculture and it's fair to point out that it's going to get better over the next thousand years, agriculture is only about 2% of the Earth's plant biomass. While the rest of the biomass will be affected by the heat and benefit from the CO2, unless we start engineering the phytoplankton and the forests and all the other plants around us, it's not going to benefit from it.

Re: Canada's gain, there is a lot of land between 50 and 70 degrees north. The questions are (a) how much land in the north are we trading for how much land in the south? and (b) how does the productivity of the northern land compare to the productivity lost in the southern land?


Re: selective breeding and genetic engineering, that's going to happen regardless of the atmospheric carbon levels

But not to tailor crops, for areas that are currently permafrost.

There are billions of acres of permafrost bogs/peat in Northern Canada. They are even a concern, for as they thaw, they offgas.

Think of these areas as you would think of coal, in terms of CO2 being released.

But! That peat and bog is immensely fertile. If, outside of the growing season length issues, warmer temperatures come, then that is very, very rich, fertile farmland.

But we need specially tailored crops, which would never be created otherwise.


Even without any genetic adaptations (probably?) the world is "greening" due to increased CO2: https://www.nasa.gov/feature/goddard/2016/carbon-dioxide-fer...


Lands with soil that support it are greening. Desertification is a continuing issue and typically do not green without human assistance.


That's not what the data says. The total leaf area has increased by 25 to 30%. And there has been no drop in global precipitation.


Err, "the data" [1] doesn't talk about increases | decreases in total land area with vegetation, the data talks about increases in green leaf area within already established areas of vegetation.

ie. Your data and the prior comment aren't necc. in conflict.

[1] https://www.nature.com/articles/nclimate3004

    We show a persistent and widespread increase of growing season integrated LAI (greening) over 25% to 50% of the global vegetated area, whereas less than 4% of the globe shows decreasing LAI (browning). 
The global vegetated area is [2]:

    About 85 percent of Earth’s ice-free lands is covered by vegetation. The area covered by all the green leaves on Earth is equal to, on average, 32 percent of Earth’s total surface area - oceans, lands and permanent ice sheets combined. 
[2] https://www.nasa.gov/feature/goddard/2016/carbon-dioxide-fer...


It's good news for maize. That's a very carbon hungry crop.


And the way we use it also creating a bunch of carbon.


In the sense that animals and human beings are big blobs of carbon, yes. Ethanol isn't the primary output of maize.


Ethanol will soon be the primary output of corn (it arguably already is). The current breakdown in the United States as of 2022 is:

- 40% goes to ethanol production

- 40% goes to livestock feed

- rest is human consumption and misc industrial uses

Source: https://www.ers.usda.gov/topics/crops/corn-and-other-feed-gr...


The growing and processing of it uses large quantities of carbon inputs. Diesel and fertilizer.


The use of those inputs isn't creating carbon, just transforming it. Carbon fueled fertilizer is also used for all other cereal crops under the sun.


If you're trying to tell me about the existence of the law of conservation of mass, I'm not sure what to tell you other than 'duh'

The point I was making is that cash crop farming is not a self-contained system even if the earth as a whole mostly is. (Much) more carbon goes into its production than comes out in the crop. Most of that takes the form of operating machinery, but there's also the production of fertilizers, and also the incremental loss of carbon in topsoil through tillage and erosion.

I am singling out maize (and, well, soy) because the scale of it is absolutely crazy; also on the whole most of the product isn't for direct human consumption (animal feed and ethanol). (Also BTW I work on software for running machinery which operates in those fields.)

Anyways, this is intrinsic to farming, which is an extractive process. The question is how to more smartly manage it in the long run.


>The use of those inputs isn't creating carbon, just transforming it

It is though. Or if you like, it's transforming carbon from "in the ground" to "not in the ground", which is fundamentally the only thing that matters, since you're adding to a closed system.


"somewhere there are probably some recessive genes just waiting for their moment to shine again"

That ... Is pseudoscience. And elsewhere is the big greening earth lie big oil was peddling circa year 2000.

The level of idiocy and denialism is incredibly depressing


I can't tell if your comment is a false flag operation. I actually tried to find it any oil executives, lobbyists, or republican said something about big greening but couldn't.


There were a lot of advertisements about " they call it pollution, we call it life" about 15-20 years ago, and I still see some billboards to that extent in PA, funded by groups like CEI:

https://www.npr.org/templates/story/story.php?storyId=542535...


Shouldn't that be "spread like weeds"


And then comes the actual wild fires


Plants also are able to make more of themselves from dirt out of pennies worth of matterial


Mostly they make themselves out of air, which is even better.

The dirt has necessary trace elements, but the carbon? That's all from CO2.


Oh man you've never cared for trees/plants have you. Some of em (most often the ones you "want") are total crybabies over those "trace elements".

You can't have DNA without phosphorus, for example, and many plants can't make nitrogen from air. Don't get me started on magnesium (needed for chlorophyll)


https://nutrients.ifas.ufl.edu/nutrient_pages/bsfpages/Essen...

    element     %, dry wt.
    oxygen      45
    carbon      44
    hydrogen    6.3
    nitrogen    1.3
    silicon     1.2
    potassium   0.9
    calcium     0.25
    phosphorus  0.16
    magnesium   0.16
    sulfur      0.15
    chlorine    0.15
    aluminum    0.11
    sodium      0.03
    iron        0.009
    manganese   0.006
    zinc        0.003
    boron       0.001
    copper      0.0005
    molybdenum  0.0001
Just CHON is 96.6% of plant mass. Adding silicon, potassium and calcium brings it up to 98.95%


Corn tissue...with a very instructive caveat emptor:

> Be aware that elemental concentrations in plant tissue can vary widely for a given crop depending on the stage of growth and environmental conditions and for different crops, yet plants can still appear normal and healthy. For some elements the range of sufficiency is wide and for others the range is narrow. A good deal of caution needs to be exercised in diagnosing mineral deficiencies based only on plant tissue analysis.

Appreciate the cite though.


That quote is talking about the way nutrients move around a plant I think, and how that introduces measurement issues depending on where and when you sample. Whereas I think this comment thread is just talking about overall composition. As in when the nutrients move from the stem to the head of a crop, if you sample the stem you would see a nutrient deficit, but actually the nutrients are still there, in the head.

That's important for farming, not that important when discussing the makeup of plants overall.

Useful sampling for crops is usually done post harvest, since that's the output and what we actually care about. Even after harvest, crops will change depending on the conditions endured during processing and shipment.


That could explain why the vegetables in Monsanto lands like America look and feel normal but have no flavor


No idea what gives an arbitrary vegetable "flavor" relative to another in the same genus. Given how much of the industry is trial-and-error breeding to objectively target certain characteristics, it's unclear that practicing experts do either.


What's your point? If I only allow you to eat C, H, O, N and their compounds, will you survive?


His point is that most of the mass comes from the air.


The ocean is 96.5% H2O, but man, I had a hard time drinking it for some reason.


Fascinating - that's lower than I would have guessed. It seems ocean water is 2.5% salts, which, yeah, is pretty damned salty compared to anything I cook...


I want to suggest re-reading their comment. “mostly they make themselves from air” and “dirt has necessary trace elements” are both 100% factually correct. The word “necessary” covers what you are saying in your comment. There’s no need to suggest they haven’t raised plants when what they said is literally correct.


I understand what you mean but the vast majority of their structure is carbon based and that comes from gaseous CO2. Can’t survive without the dirt but can’t get big without CO2


The boffins are working on self fertilizing crops now:

https://e360.yale.edu/features/indigenous-maize-who-owns-the...

It is wild that this is a thing.


It’s been a thing for hundreds of years. That’s why agriculture traditionally rotated crops and planted beans every 3rd season or so. I’m not sure what if anything is deferent about this species of corn, except perhaps that it is itself a desirable crop with more market value.

We stopped doing this and moved to artificial fertilizers in the 20th century because it vastly improved crop yields, and is cheaper.


> I’m not sure what if anything is deferent about this species of corn

This species of corn has weird roots halfway up which drip goop down on the ground. The goop contains nitrogen fixing bacteria from the soil which pull nitrogen out of the air to fertilize the soil.

It is massively different from what you say. It would vastly reduce farm runoff while increasing yields. All facts contained within the article.


I’m not sure you understand my post. Beans have the exact same nitrogen fixing bacteria in their roots too.


Beans still require extra fertilizer. This corn species does not.

Also it is corn, and not beans...? Beans is used in crop rotation in service of corn harvests. What if all of a sudden you don't have to rotate crops?

This is a big deal. Don't pooh-pooh it.


Beans have been used for thousands of years without fertilizer. They restore the nutrients in the ground by exactly the same process as this maize, because it is the exact same nitrogen-fixing bacteria at work.

I'm pooh-pooh'ing the idea because this isn't any more practical than rotating beans to restore a field was. These microbes don't fix nitrogen anywhere fast enough to supply acceptable yields. You end up with fields giving out 3-4x less end product with this strategy vs. using artificial fertilizer. You're not going to feed the worlds population with replenishing crops.


I defer to you, internet expert.


that's strictly nitrogen, which comes from the atmosphere. There are many plants that host nitrogen-fixing bacteria. Corn is not one of them. You cannot make other elements out of whole cloth unless they discover how to do transmutation in vivo. Not saying it's impossible, but we are far from there yet.


some say crop some say pest tomato tomato... really got that winter adapted hogs vibe that are causing havoc between Canada and the US


In the same vein, most of our energy comes from oxygen, not the food we eat :-)

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6379287/


Yikes sounds like decomposition.


Indeed, chemical engines, naturally aspirated. :-)


And self-repair. And self propagate. They are definitely not optimized solely for making energy.


It's kinda surprising that plant efficiency is so low, considering the absolutely massive number of plants and the hundreds of millions of years of competitive evolution to collect as much energy from sunlight as possible.


I think they just don't have any need/pressure to be more efficient than that


If you can collect more carbon, you can grow faster, letting you put big leaves to collect more light and overshadow and kill all the plants below you.

Being a plant is, locally, a winner-takes-all market.

So there is a very strong incentive for carbon-efficiency.


Hmmm, I don’t think that's accurate. To label plant ecosystems as 'winner-takes-all' really misses the forest for the trees (sorry..!). It's not all about sun-hogging; different species have unique needs and abilities, thrive in symbiotic relationships, and flourish under different conditions. For instance, take the relationship between certain fungi and tree roots, where the fungi provide the trees with hard-to-reach nutrients and, in turn, the trees supply sugars to the fungi. It's not a simple competition, it's a world full of complex interactions, adaptations and interdependencies. That's generally why we refer to these as 'ecosystems', no?


Next thing -HN guys discovers that markets aren’t any more efficient than plants are


Only of carbon is the limiting factor in your niche and not, say, nitrogen or phosphorus.


Other limiting resources dominate over energy availability for plants.


I read somewhere they don't opt for maximum efficiency turns out when it's most efficient it becomes too varied for efficient consistent atp or something, amazing stuff


Don't know where you heard that. PsI and PSII are definitely subject to lots of optimization towards efficiency.


They trade efficiency with the ability to rebuild themselves for centuries out of air.


This is fascinating. I assumed plants were far more efficient at extracting energy from sunlight but I had no reason to believe that. What is the source of this claim? Is it efficiency of a leaf in direct sunlight? Or of the entire plant with leaves wherever they may be?


What does 3 dots like this mean? I’ve been seeing it a lot recently.


Theoretical max efficiency on one particular step of the process. If you include such things as "rebuilding after a severe hailstorm" I think plants may still be impressively competitive.


Anyone know what the state of the art is/will be for panel lifetimes? Efficiency is great, but I’d sacrifice some if it meant 50+ year lifetimes of 85%+ peak output.


I have worked as a solar scientist researcher for some time, have coauthored 3 papers in Michael Graetzel[1]'s laboratory and I have some experience in both Graetzel cells and perovskite solutions like the one mentioned in this article.

Long story short: scientific researchers, especially those in well funded laboratories are incentivized by the wrong metrics (in all fields, not unique to solar) and in this field the only metric that matters is efficiency. It doesn't matter if your cell decays by 50% in a day, it reached some great potential in a new way, here's the way for a high impact publication.

Want to work on the other problem though? Lifetime, resiliency? Cheap and affordable and non-toxic materials?

Good luck getting proper funding and exposure. Why? Because scientific papers are a closed mafia, where a set of the most influential scientists (doesn't matter how many scientists the planet has, the moment you start entering a niche the number of people is very low) in their field review the submitted papers. Don't have high efficiency or you're not breaking science? Forget a high-impact journal. You're back at B-tier, C-tier papers, but those won't get you funding and status. Not great for your career.

So what do you do? You play fool and focus your efforts and many many millions of euros to get the next perovskite cell that can reach high 20%s with some twist at least or go for the 30%+ ones.

Just to express how sad and toxic the world of scientific research is (not even mentioning the insane amount of fake data that gets published every day, the politics, etc): instead of being a researcher I now prefer being a web developer writing forms list and tables.

[1] https://en.wikipedia.org/wiki/Michael_Gr%C3%A4tzel


Crystalline silicon cells are already inexpensive, non-toxic, and long-lived. So it makes sense that most researchers are looking for higher efficiency. Back when purified silicon prices spiked around 2007-2008 there were a lot of efforts looking into more affordable (if less efficient) thin film based materials, but those fizzled out as wafered silicon got cheap again and kept widening the efficiency gap over e.g. amorphous silicon.

Since there's also a much bigger solar industry today than in 2007, you also see more practically-minded research coming out of corporate centers (Longi, Oxford PV, GCL System Integration, and others working on perovskite cells and perovskite-silicon tandems). Since they care about shipping real products, they are focused on solving lifetime and durability issues. Of course since this research can give a big commercial edge as single junction silicon reaches its efficiency limits, you'll also only see the really promising work published after it is patented.


> So it makes sense that most researchers are looking for higher efficiency.

It makes sense that researchers should be considering metrics other than efficiency as well for new materials or architectures, and there's no reason why this is a uniquely industrial pursuit.

Grandparent's comment resonates - efficiency claims seem to be the only ones generating press releases.


Silicon is far from non-toxic to produce (requires insane amount of heat and chemicals to be purified) and dispose.


Could you list some of these chemicals? A quick google search only came up with pretty benign standard industrial chemicals. Disposal is a complete non-issue since the cells are inert and non-toxic (though recycling probably makes more sense than dumping them somewhere).


All these factors are reflected in the price and yet ordinary silicon PV panels are still dominating the market.


Environmental, social and ecological issues are externals and are basically never included in the price.


I am not a solar researcher. I'm just an average-joe solar user. I've been doing my own research into "what do I want" for a year now.

One thing I've found frustrating is that solar installers don't seem to understand, or want to share, the fundamentals. They do it one way, the cookie cutter way.

For example, most sites are space-constrained and that leads to concern about efficiency. I'm less space constrained, but that doesn't seem to change their ideas.

Most people have fixed-pitch roofs, so angles are what they are. Being flat, I choose the angle, and direction. There's very little data though on the best angles or the best direction. Are adjustable angles useful? Should I bias the direction to the west to compensate for morning/afternoon consumption patterns? All i get are blank stares.

On the up side, being forced to figure it out is interesting. And over the next few years I can generate actual data, testing various approaches, to see what actually is the most useful approach.

Sure, panel efficiency gets all the glory, but there's a lot more involved once you start building a system, and I think more practical research could be done there.

[1] one interesting point is the cost of the frame versus the cost of the panel. If I just "lie the panels flat" the frame price is negligible. Sure the panels are less productive, but Does spending the frame money on more panels offset that? Is overall production (not effeciency) better or worse? Factoring in summer as well as winter production.

[2] my city allows me to feed power into the grid, giving me about 40% credit. They are effectively a very large, 40% efficient battery, with no capital cost or maintainence cost. Plus they are long term, I can "charge" the battery in summer, use it in winter. I've yet to find an installer though that understands why this is good - they all balk when I say 40%.


FWIW I did my own solar installation, 50 panels in four different orientations (set of 18, two sets of 8 and two more sets of 8). This takes care of spreading the peak around solar noon at the expense of some of that peak. My panels are at 'inefficient angles', but they start generating very early in the morning and they finish really late.

When you look at it from a financial perspective in a net metering setup it is a bit less efficient, but when you look at it as if netmetering no longer exists (which I expect will happen here soon) then it suddenly comes out way ahead. It also has the added advantage that it avoids generating a lot of power when the power price is potentially negative.

My daily surplus in summer months is 80 KWh give or take, but during the winter, even with all this generating capacity I'm still running short. But proper insulation helped to cut down the gas consumption considerably and now energy costs for the whole house (about 2000 sq ft, freestanding) is < 300 euros / month including last winter's gas prices. Next winter should be better still (because I now have 18 more panels).

Total installed capacity is 16 x 265 (older panels) and 34 x 370 (newer, glass-glass panels). Inverter capacity is 4 KW on the high roof and 17 KW on the low one, with about 12 KW of output during the peaks in the summer.

Best day of the year so far made 99.8 KWh, worst days can be a few KWh so then you really need the grid. Average power draw of this house when we're careful is ~300 Watt, but cooking is a pretty big (and usually short) exception to that as is running the water cooker (but that's only a minute or two and during the day doesn't begin to approach the amount of power generated).

One downside of having panels flatter is that they foul up, some 3d printed clips helped with that but it isn't perfect.


Great info thanks. I'm starting with 20 panels, 480w, and a 16kw inverter, so room to add more panels next year if it makes sense. I figure after 2 years of actual data I'd be able to design the perfect setup for this building :)

I've heard of the flat-flat problem of pooling water, so I'd likely be at least 10 degress of angle.


Those little clips make a big difference. They use capillary action to help remove the standing water from the edges and work like a charm.

20x480 is a pretty good system to start with! And yes, insight comes with time, I'm lucky in that I already did a ton of this stuff while in Canada 20 years ago so now I can re-use that knowledge. One of the better things I did here is to create a covered space next to my garage that uses the panels as roofing. Two birds with one stone: very nice covered space and glass-glass panels allow some light to shine through and it helps keep the panels cool because there is plenty of airflow underneath them. Mounting them flush with some polymax in between to make it all watertight was a bit of a job though.


I disagree that science has the wrong incentives. The place for science is to chase new (e.g.) physics, not build something useful.

As a society we have decided that (e.g.) physics should/shall solve our problems with better technology. But that is not what pure academic science is about, or what pure academic scientists care about.

You want to iteratively improve technologies? Give more funding to proper engineers, not physicists/chemists, even if they're sometimes in the 'school of electrical engineering'.


Lifetime, resiliency, non-toxic structure are different dimensions to efficiency and there are likely trade offs between them. Those all can involve what you call “new physics” but parent points out only one gets funding: efficiency. Which parent also points out is suboptimal for society.


Parent claimed only one gets funding, but that is wrong. Industry, capitalist companies work on the other stuff all the time. Parent is likely wrong about researchers not getting funding for that other stuff also, parent likely had trouble getting funding himself due to bad attitude and blames it on other factors.


I like how you decided to trash years of my life and experience and made up a scenario where I'm motivated by envy or failure (and even faulty of bad attitude) behind your keyboard because my experience doesn't fit your views.

If you've been in this field, I'll gladly listen to your experience.


Seconded. It's weird to see your clearly well motivated and insider perspective trashed like that.

FWIW you've helped me understand some of why we keep seeing these efficiency publications that never make it to production. What is impressive is the degree to which cost has reduced as a result of economies of scale and I wonder what the bottom is there. Compared to the price of solar panels even 16 years ago (when I did my previous large installation) it is amazing to be able to get panels at todays' prices for what I perceive to be much better quality panels.

But inverter quality seems to have gone down compared to what I was buying back then, though they too are cheaper.


Are you in the Bay Area? If so, we should plan a coffee.


What do you think of MEG/singlet fission cells?


You are way out of line with this comment, please don't do this because it makes both you and HN look bad.


'Proper engineers' often have no interest in actually understanding the underlying processes, which would make for more than iterative improvements. Industry can fund iterative improvements. Source: Marc Baldo telling me to wait until my paper was published/on the arXiv and then he would 'look at it', while in the meantime trashing simulations and theory in his press releases.


Fair enough. The point of my comment was the incentives are set up in 'science' to research fundamentals (I don't think there are many interesting fundamentals in degradation, but I may be wrong). I am arguing there should be a separate stream of funding/researchers with incentives to work on other types of problems.

Scientists tend to be interested in 'neat cool solutions' or 'neat cool problems' and there should be separate funding for 'important problems with boring solutions' that sits separately to current science funding. I agree leave the small-scale iteration to industry.


> Give more funding to proper engineers, not physicists/chemists

Materials science departments are often called "Materials Science and Engineering". How do they fall in your categorization?

Without disrespect intended, your words sound like those of someone who has never spent any time in graduate school in a engineering program in physical disciplines. The lines can be blurry.


I get that. Perhaps things are different in different countries, but where I am materials science/eng is drastically underfunded for this reason.

My comment was worded strongly, I meant more that funding could come from different streams fo4 different purposes.


A scientist is someone who follows the scientific method for one, engineers do that too. You can be both


There is no agreed upon definition of science or the scientific method. I'm sure we could agree upon a demarcation between scientist and engineer, though, and I was drawing that distinction in a way I think we can all intuit.


I’m not sure that demarcation is easy. As I understand it, the Manhattan Project (for instance) was science Monday, engineering Tuesday, and usually by the same people.


Applied sciences are a thing, you know ...


They are! And they receive fewer funds in my neck of the woods.


They essentially last 50+ years now, and have always, barring damage. State of the art panels today warranty 90%+ output after 25 years. So they probably aren't far off what you're asking for at 50. They keep getting better and cheaper every year.


NREL's latest data is summarized here:

https://www.nrel.gov/docs/fy22osti/81172.pdf#page=5

Some types of panels have increased capacity after being in the field for years. Degradation is not a significant economic concern at this stage of the process.


I see degradation numbers between -0.1%/year and -1.1%/year.

This translates to about

* 0.999^25 = 97.5% to 0.989^25 = 75.8% output after 25 years.

* 0.999^50 = 95% to 0.989^50 = 57.5% output after 50 years.


It would be good to break the figures down between:

* The actual silicon is degrading

* The cover glass is getting dirty/frosted/delaminating/optical adhesive is no longer clear

* Electrical failure of a whole cell - for example it is cracked, yet the panel still appears to work due to the bypass diodes removing a whole cell from the circuit.

Sure - from the users point of view it doesn't matter, but from an engineering point of view, the cause of failure gives some clues how to prevent it.


Data I’ve see doesn’t show output dropping continuously at a constant rate. Also some panels did show modest improvement for a few years.


> modest improvement for a few years.

Many regions of the world are getting dryer. You might just be seeing a global warming side effect as there is less cloud cover.


This is true for panels on the market now, and most of those produced in the past. The 33% tandem systems reported on by Ars Technica see severe efficiency degradation after just a few hundred hours of full-power operation, so that's something that needs to be solved before perovskite-on-silicon tandem systems enter mass production.


What about hail damage? That's the main concern holding me back, but is this something already being addressed?


That sounds like you want armoured panels; As I understand it, the degradation being discussed here is from the light itself.


Most panel warranties cover hail up to like 1" diameter. So, pretty sizable. Beyond that, you need insurance.


You can always put more/stronger glass on top to protect them more.

But I would bet it is cheaper to buy insurance for such infrequent events.


Is it possible to put some translucent protective material that doesn't block the frequencies the panels absorb?


yes, they use this new tech called glass.


Glass refracts and depending on what it's made of, will absorb some frequencies.

> For normal incidence, approximately 4 % of the light is reflected; this value is determined by the refractive index of the glass. For most glasses with a refractive index of 1.5, reflection losses at the surface result in an approximate 4% decrease in light intensity.


Consumer panels on homes have hail protection since forever.


I'm the opposite, I'd trade some of the current longevity, for ever increasing efficiency.

Some research suggests you should replace all solar panels every 17 years because the tech will have advanced enough to make it worthwile.


There are very reputable manufacturers now that warranty on a sliding scale over time to be 84% of original STC watt rating at 25 years.


Does 33% efficiency means it can generate 3.3kW per m^2?!


330 watts. Sunlight is about 1000 watts per square meter at noon on a clear day.


That might be easy to remember for baseline calculations but it’s actually more like 1,360 watts per square meter.

So a smidge below 450W at 33%


That's above the Earth's atmosphere. At sea level it's about 1000 watts:

https://acee.princeton.edu/wp-content/uploads/2017/09/SolarD...

The intensity of the Sun’s energy is about 30 percent greater at the top of the atmosphere, but various gases and aerosols reduce the intensity by absorbing sunlight as it travels through the atmosphere toward the Earth’s surface. Where the Earth’s surface is flat on a clear day at sea level, with the Sun directly overhead, the average intensity of direct sunlight is about 1,000 watts per square meter.

Satellites have modestly better solar resources to work with since there is no atmospheric attenuation.


It depends on the absorption bands used. One big downside of PV cells is they don't use energy in the blue. Perovskites do absorb blue. So a combo should do better than either alone.

The average intensity of solar energy reaching the top of the atmosphere directly facing the Sun is about 1,360 watts per square meter.

You get about 1,000 W per square meter at sea level https://www.solar-electric.com/learning-center/solar-insolat...


At sea level it varies so much depending on local climate & atmospheric conditions—even during the same day—that it’s not really helpful for calculations.

The mean global average is between 164 watts to 340 watts per square meter over a 24-hour day, for example.


Where I live, in a desert with a rain shadow ensuring clear skies most days? Sure, in my solar design class we took out a lightmeter and measured 1200W/m^2. Maybe on a good day it could push 1300W/m^2.

In many other climates, 1000 is honestly a generous estimate. (Presumably they're aware and that's why they hedged by specifying peak power).


Ahh you’re right, for some reason my head thought it was 10 kW.


Taking the long term view solar panels of some sort seem like the energy technology pattern that will dominate the Earth's antropocene period.

Other patterns (wind, hydro, geothermal etc) feel clumsy, high maintainance and localized. Tapping secondary feeds rather than the universal primary feed.

For sure, solar panel efficiency, total environmental impact, economic costs of manufacturing and recycling, storage etc are all relevant dimensions. They see much attention and, inevitably, innovation.

In the scheme of things the fossil fuel binge will be but a blip, succeeded by a long period where humanityp enters its solar powered phase.


The "fossil fuel binge" has driven so many species extinct that there is no chance it will be a "blip".


Species will continue going extinct. Its the anthropocene. Our mere presence at such large numbers in every ecosystem is having a huge impact and this will continue even conditioning on us using the most benign energy technology.

The "blip" refers to the fossil fuel induced climate change. Reaching sustainable equilibrium with other parts of the biosphere is still an open issue.


Fossil fuel induced climate change on its own is very far from being a "blip", though. I'm not a biologist or anything, but there's not a doubt in my mind that more species have died from fossil fuel induced climate change (and fossil fuel extraction, too) than anyone can even predict the consequences of.


If we manage to get rid of fossil fuels before technological society collapses from climate change, maybe.


It'd be in user's best interest but not corporation's best interest.


For every 1 pound of polysilicon generated, you create 2-4 pounds of silicon tetrachloride. Even if the cost of a panel goes to zero, it makes no difference because the costs to dispatch and transmission energy exceed the useful capacity of solar in a large % of areas where it is deployed on the grid and the specific times in the grid, you end up consuming more nat gas per kwh than if you'd just burned nat gas from start to finish.

I bought $UAN at $7-$9 and I'll continue buying between $75-$85. It's sort of a long call on natural gas - and for me a long call on ESG ridiculousness proliferating quickly.

The nat gas bull run will rise again with the wide scale institutionally backed ESG funds that get pointed toward solar deployments.


I’m sorry I lost you on the last point. Where does the natural gas consumption come from in a solar power plant, inclusive of presumably grid connectivity?

I don’t understand the chemistry you state. My understanding is silicon tetrachloride is an intermediate for producing polysilicon, and is used multiple places in the process in a recycling through the hydrogenation reactor. It’s not a by product. Do you mean to produce polysilicon you need 4x the silicon tetrachloride? That’s approximately true. But chlorinated ferrosilicon is typically the route for production and this can be achieved without natural gas, if that was where you got your nat gas assertion.



https://en.m.wikipedia.org/wiki/Silicon_tetrachloride

Read the uses section.

It doesn’t make sense that silicon tetrachloride is a byproduct of purifying silicon. Why would you leave the silicon atom attached to the chlorine if the silicon atom is what you are after. The ratio makes sense - there’s one silicon atom and four chlorine atoms, but the statement that it’s a waste product is strange to me as it’s not. It is a intermediate and you do have to house it, and you can leak it and that’s not great (but as they state in the article you linked it’s not stable around water so I wouldn’t lose a huge amount of sleep over it’s pollution.


Take a look at the site he linked in his profile: https://engineersf.com/energy/

>I’m of the mindset that you should be weary of and ignore the comments of software developers, physicists, and electrical engineers’ viewpoints on the hard sciences unless the prove otherwise as it relates to energy.

Ah yes, physicists viewpoints on the hard sciences are particularly untrustworthy.

And here is the claim mentioned above:

>For every 1 pound of polysilicon you make, you make 4 pounds of the nasty stuff-silicon tetrachloride.

>Okay, so some green hippie nutbags will tell you that you can just recycle this silicon tetrachloride stuff into new polysilicon because it requires less energy, but that’s bullshit because it costs a lot to do so.

Wow! Very convincing arguments!

Ok now a random google search:

https://www.globenewswire.com/news-release/2021/03/05/218770...

>Silicon tetrachloride is the colorless inorganic fuming liquid and is used to produce high purity silicon. It can be produced by using several methods and compounds including chlorine, metal silicon, and coke among others. Moreover, it can be also produced as a byproduct after treating metallurgical grade silicon to form polysilicon. For each ton of polysilicon, 3-4 tons of silicon tetrachloride is generated. Polysilicon manufacturer’s further process the waste silicon tetrachloride generated and reuses it after processing. This saves the energy cost and raw material cost however, required an expensive set of machinery to process waste silicon tetrachloride.

Wait a minute. So there is one process where it is an undesired byproduct and another process where it is actually the primary input?

>Hence polysilicon manufacturers prefer silicon tetrachloride instead of raw silica to save on cost, energy, and time. Moreover, the government from various countries has enforced laws to prevent unauthorized dump of toxic silicon tetrachloride. For instance, in China, 98.5% silicon tetrachloride produced as a byproduct is required to be recycled which compels manufacturers to adopt silicon tetrachloride as a raw material for polysilicon production.

Turns out China is a green hippie nutbag country.


Ah thanks. I felt like I had lost my mind there for a bit.


When the sun stops shining, natural gas peaking plants are the backup.


It's not too difficult to replace that natgas with hydrogen. I also don't see how burning gas only when the sun doesn't shine consumes more gas than burning gas all the time...


Batteries are already eating the lunch of natural gas peaking plants, and as time goes on the economics are going to tip ever further in favor of batteries.

Natural gas is a transition fuel, not the end game.


Unless it is batteries and battery-like hydro.




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